First, mount the vhd using

Mount-WindowsImage -ImagePath C:\VHDs\BigHomies.vhdx -Path C:\VHDMount -Index 1

Capture WIM file

New-WindowsImage -CapturePath C:\VHDMount -Name Win10Image -ImagePath C:\CapturedWIMs\Win10.wim -Description "Yet another Windows 10 Image" -Verify`

And let it do it’s thing. When you are done you can unmount the vhd and discard any changes using:

Dismount-WindowsImage -Path C:\VHDMount -Discard